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such as decomposers of hydroperoxides, are used to transform labile intermediates into more stable compounds, thus preventing their photodecomposition and the formation of free radicals An important type of inhibition is the scavenging of free radicals that have been allowed to form Photostabilizers are used in very low concentrations but can signi cantly lengthen the lifetime of most organic polymeric materials They are generally classi ed according to their principle mode of action However, some stabilizers contribute to the protection of polymers by more than one mechanism For example, hydroxyphenylbenzotriazoles deactivate the excited states of carbonyl groups in addition to screening UV radiation Initially, only screening agents and UV absorbers were available as light stabilizers Later, nickel chelates offered additional protection, but the introduction of sterically hindered amine light stabilizers (HALS), developed more than 20 years ago, signi cantly advanced the ability to protect polymers against the environment.

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Angle of incidence,

and the t of kobs [OH ] data, obtained in several experiments carried out at constant [OH ], gives the term kOH (Figure 2). These dependence functions, where concentrations are concerned, can be of great complexity but they are very important information for the formulation of the reaction mechanism [1, 3, 7, 8]. When the parameter is the ionic strength the dependence function is given by the Br nsted Bjerrum equation (8) [1, 7, 8, 15], where k0 is the rate constant at zero ionic strength, a is a constant (for water at 25 C, a = 0.50925 L1/2/mol1/2 [16]) and ZAZB is the product of charges of the reacting species taking part in the ratedetermining step: kobs = k0 10

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R2 is the same value as X. Thus, the outcome of a sequence of two XORs using the same value produces the original value. To see this feature of the XOR in ...

For effective stabilization, the additives should have optimum physical properties, such as solubility in the polymer, resistance against volatility and leaching, compatibility with the polymer and other additives, and good photostability Physical incompatibility can result in signi cant loss of the stabilizer from the polymer, particularly from thin specimens [68] In the past two decades improvements have focused on developing low volatility, higher molecular weight stabilizers, as well as some with functional groups that could be grafted to the polymer to reduce stabilizer loss A recently introduced approach to reduce volatility and extractability, which has shown some promise, is the grafting of a variety of classes of stabilizers to polysilanes with functional groups [69] Thermal stabilizers used during processing and fabrication play an important role in protecting polymers against environmental effects by reducing the formation of ultraviolet absorbing impurities that sensitize and accelerate degradation under service conditions.

G F (+s, e) ( s, +e)

below. Moreover, central obesity, as measured by waist circumference or WHR, is in general, a better predictor of all-cause as well as cardiovascular mortality, as compared with the generalized obesity measure of BMI (Folsom et al., 2000; Kanaya et al., 2003).

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A wide range of transformations can be applied to spectral data before they are analyzed. The main purpose of transformations is to make the latent variables better available for powerful analysis. One of the most widely used is logarithmic transformation, which is especially useful to make skewed variables more symmetrically

Thermal stabilizers that are photochemically stable also protect polymers against thermooxidation by the environment However, this section is primarily concerned with the stabilizers that either screen or interfere with the photochemical effects of solar radiation..

Computers typically work with two types of images: raster and vector Raster images (also known as bitmap images) are made up of pixel data; in a 20-pixel-wide by 20-pixel-high color image there are 400 individual pixels making up the image, and each of these pixels has its own RGB color value In contrast, a vector image uses mathematical equations to describe the shapes that make up the image The SVG (Scalable Vector Graphics) format is a good example of a vector image Vector images are great for diagrams that include lines, curves, and blocks of color, but are not suitable for photographs or images with lots of detail In this chapter you concentrate on working with raster images, which tend to be more common on the Web.

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